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Essay

Asymmetric Epoxidation Of Dihydronaphthalene With A Synthesized Jacobs

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Issue:

Science

 

Written by:

Hazel C

 

Date added:

January 9, 2016

 

Level:

University

 

Grade:

A

 

No of pages / words:

8 / 2218

 

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2006 times

 

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Essay content:

The synthesized Jacobsen's catalyst was used to catalyze the epoxidation of dihydronaphthalene. The products of this reaction were isolated, and it was found that the product yielded 1,2-epoxydihydronaphthalene as well as naphthalene. Introduction In 1990, professor E.N. Jacobsen reported that chiral manganese complexes had the ability to catalyze the asymmetric epoxidation of unfunctionalized alkenes, providing enantiomeric excesses that regularly reaching 90% and sometimes exceeding 98% ...
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Jacobsen reported that chiral manganese complexes had the ability to catalyze the asymmetric epoxidation of unfunctionalized alkenes, providing enantiomeric excesses that regularly reaching 90% and sometimes exceeding 98% . The chiral manganese complex Jacobsen utilized was [(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2- cyclohexanediaminato-(2-)]-manganese (III) chloride (Jacobsen's Catalyst)...
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