Electrophilic Aromatic Iodination of Vanillin

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Issue:

Miscellaneous

 

Written by:

Holly L

 

Date added:

June 20, 2013

 

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Grade:

A

 

No of pages / words:

4 / 874

 

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9147 times

 

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Essay content:

Used Purpose 3-methoxy-4-hydroxybenzaldehye C8H8O3 152.1494 MP=81-83, BP=285 NA 0.1g Solute Ethanol CH3CH2OH 46.0688 MP=-114.1, BP=78.3 0.789 2.0mL Solvent Sodium Iodide NaI 149.8943 MP=661, BP=1300 3.667 0.117g Catalyst Bleach NaOCl 74.4422 MP=NA, BP=40dec 1.209 1.1mL Oxidizing Agent Sodium Thiosulfate Na2O3S2 158...
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Cool the flask in an ice bath for a few minutes. To the ice-cold solution, add 0.117 g of sodium iodide. Over a period of 10 minutes, add 1.1 mL of Bleach (5.25% w/w NaOCl) dropwise to the cooled flask. The solution should turn a yellow color. Once the addition is complete, let the solution warm to room temperature and stir for about 10 minutes...
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