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Essay

Experiment on Negative Deviation of Mixtures

Essay specific features

 

Issue:

Science

 

Written by:

Daniel R

 

Date added:

November 5, 2012

 

Level:

University

 

Grade:

A

 

No of pages / words:

2 / 542

 

Was viewed:

8684 times

 

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Essay content:

Simple distillation of solutions of cyclohexanone and TCE was followed and the refractive indices of different fractions from the vapor and the liquid were measured. The system in hand showed a strong negative deviation from Raoult's law, forming an azeotropic mixture at T = 157.5 0C (refer to plot.2)...
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By definition, a solution which behaves ideally is one in which the vapor pressure of a particular component is proportional to the mole fraction of that component in the liquid phase over the entire range of mole fractions. Note that no distinction is made between solute and solvent. Empirically it has been found that in very dilute solutions the vapor pressure of solvent (major component) is proportional to the mole fraction X of the solvent where the proportionality constant is the vapor pressure, po, of the pure solvent...
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