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Essay

Maxwell Relations

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Issue:

Science

 

Written by:

Martha D

 

Date added:

May 16, 2016

 

Level:

University

 

Grade:

A

 

No of pages / words:

7 / 1795

 

Was viewed:

9083 times

 

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Essay content:

Therefore (1-2) dU = T dS ? P dV. The differential of the accumulated internal energy in a fixed-composition, P dV ? work system is. = dH = dU + d(PV) (1-3) = dU + P dV + V dP. Substituting equation (1-2) in equation (1-3), we obtain (1-4) dH = T dS + V dP. From the defining the Helmholtz function A we obtain ( 1-5) dA = dU ? d(TS) = dU ? T dS ? S dT...
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If a property M is a function of x and y, (1.7a) M = M(x,y) then a differential change in M, dM, is the sum of the amount that M changes in the interval dx, with y held constant, plus the amount that M changes in the interval dy, with x held constant (see figure 1.1), or (1.8) dM = (M/X)y dx + (M/Y)x dy...
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