Scanning Spectrophotometer Determination of the Quantum Numbers (Initial and Final States), Wavelength, and Length of the Box Using Particle in a One Dimensional Box Model for Experimental and Computation Vibration-Rotation Spectroscopy for Carbon...

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James B


Date added:

July 29, 2014








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9 / 2331


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This is of interest in that the instrument to being used, a Fourier-transform infrared (FT-IR) spectrometer, can measure the vibrational and rotational transitions of the fundamental and first overtone of CO. Through this experiment the objective is to collect data from the aforementioned instrument in order to determine vibrational and rotational spectroscopic constants and CO’s bond length, then to compare them with quantum chemical calculation...
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To further define the above variables; ?e is the fundamental vibrational or harmonic frequency in cm–1, v is the vibrational quantum number, ?exe is the anharmonicity correction, B is the rotational constant in cm?1, I is the moment of inertia, r is the internuclear distance, ?e is the rotation-vibration interaction parameter, and De is the dissociation energy...
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